01 - Preheat oven to 400°F. Lightly coat a large baking dish with 1 tablespoon of olive oil, spreading it evenly across the bottom and sides.
02 - Arrange the sliced red, yellow, and green bell peppers along with the red onion in an even layer across the prepared baking dish. Drizzle with the remaining 1 tablespoon of olive oil, then sprinkle with half of the salt, black pepper, Italian seasoning, and smoked paprika. Toss the vegetables gently to ensure even coating.
03 - Pat the chicken breasts dry with paper towels. Season both sides of each breast with the remaining salt, black pepper, Italian seasoning, and smoked paprika, pressing the spices gently into the meat. Lay the seasoned chicken breasts on top of the vegetable bed in the dish.
04 - Scatter the minced garlic evenly over the chicken and vegetables. Cover the baking dish tightly with aluminum foil and bake for 20 minutes, allowing the chicken to cook in the steam alongside the vegetables.
05 - Remove the foil and sprinkle the mozzarella and Parmesan cheeses evenly over each chicken breast. Return the dish to the oven uncovered and bake for an additional 10 minutes, or until the chicken registers 165°F internally and the cheese is fully melted with a golden, bubbly surface.
06 - Remove the dish from the oven and let the chicken rest for 5 minutes before serving. This allows the juices to redistribute for a more tender, flavorful result. Serve the chicken over the roasted peppers and onions.